staggered conformation sentence in Hindi
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- Rotation away from the staggered conformation interrupts this stabilizing force.
- Both of these staggered conformations are much more stable than the eclipsed conformations.
- Here they are shown in a staggered conformation.
- More complex molecules, such as butane, have more than one possible staggered conformation.
- For example, ethane ( C 2 H 6 ) has three equivalent staggered conformations.
- X-ray crystallography confirmed that octaphenylrhodocene has a sandwich structure with a staggered conformation.
- Despite this apparent freedom, only two limiting conformations are important : eclipsed conformation and staggered conformation.
- The barrier of rotation between staggered conformations of ethane is approximately 2.9 kcal / mol.
- Two of these are recognised as energy minimum ( staggered conformation ) and energy maximum ( eclipsed conformation ) forms.
- The energetic stabilization of this effect is maximized when the two orbitals have maximal overlap, occurring in the staggered conformation.
- Torsional strain occurs when atoms separated by three bonds are placed in an eclipsed conformation instead of the more stable staggered conformation.
- It had been accepted as early as the 1930s that the staggered conformations of ethane were more stable than the eclipsed conformation.
- The analysis of the curves determined that the staggered conformation had no connection to the amount of electrostatic repulsions within the molecule.
- The staggered conformation is more stable by 12.5 mol than the eclipsed conformation, which is the energy maximum for ethane.
- In contrast to ferrocene, wherein the cyclopentadienyl rings are in a staggered conformation, those of ruthenocene crystallise with an eclipsed conformation.
- These results demonstrate that Coulombic forces do not explain the favored staggered conformations, despite the fact that central bond stretching decreases electrostatic interactions.
- In the staggered conformation, one C-H sigma bonding orbital donates electron density to the antibonding orbital of the other C-H bond.
- The crystal structure of octaphenylrhodocene shows a staggered conformation ( similar to that of ferrocene, and in contrast to the eclipsed conformation of ruthenocene ).
- As far back as 1890 1891, chemists suggested that ethane molecules preferred the staggered conformation with the two ends of the molecule askew from each other.
- Wilson had proven that the energy barrier between any pair of eclipsed and staggered conformations is approximately 3 kcal / mol, and the generally accepted rationale for this was the unfavorable steric interactions between hydrogen atoms.
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